6 Disks...(2) 3 disk Raid-Z1 or (1) 6 disk Raid-Z2?

More precisely: Add a first drive, let it extend and scrub afterwards; then add the second drive, and let the second scrub finish. Do not attempt to cut corners or to add two drives at the same time, the result appears to be “undefined”.
Then run the rebalancing script to rewrite the data with the new stripe width.