The Buildin apps don’t have a way to add a network to them. You could install portainer from the apps catalogue. The buildin apps can be edited in the portainer gui and there you can add another network.
I honestly don’t know since i don’t use the build ini apps system of truenas. I’m running my stack inside a scale-jail (nspawn-container) and when incus has matured a bit more will migrate to incus.