This might be fixed by setting a suitable TLER vallue.
But the pool has several flaws.
sda Barracuda CMR 2 TB — OK
sdb Barracuda Green 2 TB — check TLER (and other drives as well)
sdc Barracuda SMR 2 TB — should be replaced as soon as possible
sdd Barracuda Green 2 TB — 10.5k reallocated sectors, this drive is degrading, and this is another possible cause of slowdowns; replace immediately, RMA if possible