I had to go back and figure out how my TrueNAS sends emailed alerts. I found the SMTP settings in System Settings → General → Email. What I did not find there is the email address where messages are sent. I am receiving such messages, so I must have set it up originally. Where can I find that config item?
System Settings → Alert Settings
That would be the email account for your admin user
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In that case it should be as @DjP-iX mentioned, the email address for your admin user.
EDIT: Ah, hadn’t seen your reply, glad to see you got it sorted
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